![54. Synthesis of 4-(2,2-Difluorovinyl)benzonitrile through a Wittig-type Olefination of 4-Formylbenzonitrile](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/1735829870222-IX5G5OT5AYVBQUZJZMZC/54+TAR.png)
54. Synthesis of 4-(2,2-Difluorovinyl)benzonitrile through a Wittig-type Olefination of 4-Formylbenzonitrile
Andrew J. Intelli; Jacob P. Sorrentino; and Ryan A. Altman*
![51. Palladium and Copper Co-Catalyzed Chloro-Arylation of gem-Difluorostyrenes – Use of a Nitrite Additive to Suppress β-F Elimination](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/1728394442485-PXBJDHTQ439T9E3FV4BT/51+TAR+corrected.png)
51. Palladium and Copper Co-Catalyzed Chloro-Arylation of gem-Difluorostyrenes – Use of a Nitrite Additive to Suppress β-F Elimination
Intelli, A. J.; Wayment, C. Z.; Lee, R. T.; Yuan, K.; Altman, R. A.*
![49. Peroxide-Initiated Hydrophosphination of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/3ac77a55-4769-4212-a869-623711ee9156/49+TAR.png)
49. Peroxide-Initiated Hydrophosphination of gem-Difluoroalkenes
Intelli, A. J.; Lee, R. T.; Altman, R. A.*
![47. A Diselenide Additive Enables Photocatalytic Hydroalkoxylation of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/8652409f-9cb2-410d-af0f-2ae235d683c3/47+TAR.png)
47. A Diselenide Additive Enables Photocatalytic Hydroalkoxylation of gem-Difluoroalkenes
Herrick, R. M.; Abd El-Gaber, M. K.; Rodriguez, L. G. C.; Altman, R. A.*
![46. Photocatalytic Hydrothiolation of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/9a4f11f8-8dd2-4fae-9a4b-048b2daa89df/46+TAR.png)
46. Photocatalytic Hydrothiolation of gem-Difluoroalkenes
Sorrentino, J. P.; Herrick, R. M.; Abd El-Gaber, M. K.; Abdelazem, A. Z.; Altman, R. A.*
![45. Cu(II)-Catalyzed Oxidation of gem-Difluoroalkenes Generate α,α-Difluorinated-α-Phenoxyketones](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/44ff55d6-3f2d-4044-a50a-20110ec73d0b/45+TAR.png)
45. Cu(II)-Catalyzed Oxidation of gem-Difluoroalkenes Generate α,α-Difluorinated-α-Phenoxyketones
Koley, S.; Cayton, K. T.; González-Montiel, G. A.; Yadav, M. R.; Orsi, D. L.; Intelli, A. J.; Cheong, P. H.-Y.;* Altman, R. A.*
![42. Fluorine-Retentive Strategies for the Functionalization of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/a1dfb5a2-ab2b-4706-a68a-cb9a5a1262b6/42+TAR.png)
42. Fluorine-Retentive Strategies for the Functionalization of gem-Difluoroalkenes
Sorrentino, J. P.; Altman, R. A.*
![41. Acid-catalyzed Hydrothiolation of gem-Difluorostyrenes to Access α,α-Difluoroalkylthioethers](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/4427f848-153c-449d-a4fb-7849439f2559/41+TAR.png)
41. Acid-catalyzed Hydrothiolation of gem-Difluorostyrenes to Access α,α-Difluoroalkylthioethers
Sorrentino, J. P.; Orsi, D. L.; Altman, R. A.*
![39. Arylation of gem-difluoroalkenes using a Pd/Cu Co-catalytic system that avoids β-fluoride elimination](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/b5b322cc-7fc4-4c5c-a481-f8a9e2999557/39+TAR.png)
39. Arylation of gem-difluoroalkenes using a Pd/Cu Co-catalytic system that avoids β-fluoride elimination
Yuan, K; Feoktistova, T.; Cheong, P. H.-Y.;* Altman, R. A.*
![38. Cobalt-Catalyzed Selective Unsymmetric Dioxidation of β,β-Difluorostyrenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/bcaf965c-8928-40ec-8786-aee93c01120b/38+TAR.png)
38. Cobalt-Catalyzed Selective Unsymmetric Dioxidation of β,β-Difluorostyrenes
Orsi, D. L.; Sorrentino, J. P.; Douglas, J. T.; Altman, R. A.*
![36. Recent Advances in Transition Metal Catalyzed Functionalization of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/000b06e1-19c9-4361-99fc-19660965595c/36+TAR.png)
![32. Organocatalytic Strategy for Hydrophenolation of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/8051a22c-10be-4b86-aaa2-d5548256cee0/32+TAR.png)
32. Organocatalytic Strategy for Hydrophenolation of gem-Difluoroalkenes
Orsi, D. L.; Yadav, M. R.; Altman, R. A.*
![25. Base Catalysis Enables Access to α,α-Difluoroalkylthio-ethers](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/3270c18b-c885-4354-bc42-00bb15a8fcb1/25+TAR.png)
25. Base Catalysis Enables Access to α,α-Difluoroalkylthio-ethers
Orsi, D. L.; Easley, B. J.; Lick, A. M.; Altman, R. A.*
![18. Metal-free Trifluoromethylation of Aromatic and Heteroaromatic Aldehydes and Ketones](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/052327fa-3fb7-49fe-98b5-fd5022f472d5/18+TAR.png)
18. Metal-free Trifluoromethylation of Aromatic and Heteroaromatic Aldehydes and Ketones
Qiao, Y.; Si, T.; Yang, M.-H.; Altman, R. A.*
![13. Preparation of Fluoroalkenes via the Shapiro Reaction: Direct Access to Fluorinated Peptidomimetics](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/4d582bb9-3da4-4316-bacc-eb2878850783/13+TAR.png)
13. Preparation of Fluoroalkenes via the Shapiro Reaction: Direct Access to Fluorinated Peptidomimetics
Yang, M. H.; Matikonda, S. S.; Altman, R. A.*