![55. A Deoxyfluoroalkylation-Aromatization Strategy to Access Fluoroalkyl Arenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/1736548946452-Y5FD9MCE6Z1EDT7G26EB/55+TAR+corrected.png)
55. A Deoxyfluoroalkylation-Aromatization Strategy to Access Fluoroalkyl Arenes
Bhattarai, P.; Koley, S. K.; Goel, K.; Altman, R. A.*
![54. Synthesis of 4-(2,2-Difluorovinyl)benzonitrile through a Wittig-type Olefination of 4-Formylbenzonitrile](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/1735829870222-IX5G5OT5AYVBQUZJZMZC/54+TAR.png)
54. Synthesis of 4-(2,2-Difluorovinyl)benzonitrile through a Wittig-type Olefination of 4-Formylbenzonitrile
Andrew J. Intelli; Jacob P. Sorrentino; and Ryan A. Altman*
![51. Palladium and Copper Co-Catalyzed Chloro-Arylation of gem-Difluorostyrenes – Use of a Nitrite Additive to Suppress β-F Elimination](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/1728394442485-PXBJDHTQ439T9E3FV4BT/51+TAR+corrected.png)
51. Palladium and Copper Co-Catalyzed Chloro-Arylation of gem-Difluorostyrenes – Use of a Nitrite Additive to Suppress β-F Elimination
Intelli, A. J.; Wayment, C. Z.; Lee, R. T.; Yuan, K.; Altman, R. A.*
![50. Deoxytrifluoromethylation/Aromatization of Cyclohexan(en)ones to Access Highly Substituted Trifluoromethylarenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/3d24890a-cc6e-45bf-a7a9-0d17a2ec133f/50+TAR.png)
50. Deoxytrifluoromethylation/Aromatization of Cyclohexan(en)ones to Access Highly Substituted Trifluoromethylarenes
Bhattarai, P.; Abd El-Gaber, M. K.; Koley, S.K.; Altman, R. A.*
![49. Peroxide-Initiated Hydrophosphination of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/3ac77a55-4769-4212-a869-623711ee9156/49+TAR.png)
49. Peroxide-Initiated Hydrophosphination of gem-Difluoroalkenes
Intelli, A. J.; Lee, R. T.; Altman, R. A.*
![48. Palladium-Catalyzed Dearomatization of Benzothiophenes: Isolation and Functionalization of a Discrete Dearomatized Intermediate](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/d8dce436-fa2a-4010-a46a-0e865c4aa802/48+TAR.png)
48. Palladium-Catalyzed Dearomatization of Benzothiophenes: Isolation and Functionalization of a Discrete Dearomatized Intermediate
Intelli, A. J.; Pal, M.; Selvaraju, M.; Altman, R. A.*
![47. A Diselenide Additive Enables Photocatalytic Hydroalkoxylation of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/8652409f-9cb2-410d-af0f-2ae235d683c3/47+TAR.png)
47. A Diselenide Additive Enables Photocatalytic Hydroalkoxylation of gem-Difluoroalkenes
Herrick, R. M.; Abd El-Gaber, M. K.; Rodriguez, L. G. C.; Altman, R. A.*
![46. Photocatalytic Hydrothiolation of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/9a4f11f8-8dd2-4fae-9a4b-048b2daa89df/46+TAR.png)
46. Photocatalytic Hydrothiolation of gem-Difluoroalkenes
Sorrentino, J. P.; Herrick, R. M.; Abd El-Gaber, M. K.; Abdelazem, A. Z.; Altman, R. A.*
![45. Cu(II)-Catalyzed Oxidation of gem-Difluoroalkenes Generate α,α-Difluorinated-α-Phenoxyketones](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/44ff55d6-3f2d-4044-a50a-20110ec73d0b/45+TAR.png)
45. Cu(II)-Catalyzed Oxidation of gem-Difluoroalkenes Generate α,α-Difluorinated-α-Phenoxyketones
Koley, S.; Cayton, K. T.; González-Montiel, G. A.; Yadav, M. R.; Orsi, D. L.; Intelli, A. J.; Cheong, P. H.-Y.;* Altman, R. A.*
![42. Fluorine-Retentive Strategies for the Functionalization of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/a1dfb5a2-ab2b-4706-a68a-cb9a5a1262b6/42+TAR.png)
42. Fluorine-Retentive Strategies for the Functionalization of gem-Difluoroalkenes
Sorrentino, J. P.; Altman, R. A.*
![41. Acid-catalyzed Hydrothiolation of gem-Difluorostyrenes to Access α,α-Difluoroalkylthioethers](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/4427f848-153c-449d-a4fb-7849439f2559/41+TAR.png)
41. Acid-catalyzed Hydrothiolation of gem-Difluorostyrenes to Access α,α-Difluoroalkylthioethers
Sorrentino, J. P.; Orsi, D. L.; Altman, R. A.*
![39. Arylation of gem-difluoroalkenes using a Pd/Cu Co-catalytic system that avoids β-fluoride elimination](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/b5b322cc-7fc4-4c5c-a481-f8a9e2999557/39+TAR.png)
39. Arylation of gem-difluoroalkenes using a Pd/Cu Co-catalytic system that avoids β-fluoride elimination
Yuan, K; Feoktistova, T.; Cheong, P. H.-Y.;* Altman, R. A.*
![38. Cobalt-Catalyzed Selective Unsymmetric Dioxidation of β,β-Difluorostyrenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/bcaf965c-8928-40ec-8786-aee93c01120b/38+TAR.png)
38. Cobalt-Catalyzed Selective Unsymmetric Dioxidation of β,β-Difluorostyrenes
Orsi, D. L.; Sorrentino, J. P.; Douglas, J. T.; Altman, R. A.*
![36. Recent Advances in Transition Metal Catalyzed Functionalization of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/000b06e1-19c9-4361-99fc-19660965595c/36+TAR.png)
![35. Connecting Remote C–H Bond Functionalization and Decarboxylative Coupling Using Simple Amines](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/14929cbb-13e4-4cbd-bf7b-ec49beeae0b3/35+TAR.png)
35. Connecting Remote C–H Bond Functionalization and Decarboxylative Coupling Using Simple Amines
de Azambuja, F.; Yang, M.-H.; Feoktistova, T.; Selvaraju, M.; Brueckner, A. C.; Grove, M. A.; Koley, S.; Cheong, P. H.-Y.;* Altman, R. A.*
![33. BBDFA: A Practical Reagent for Trifluoromethylation of Allylic and Benzylic Alcohols on Preparative Scale](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/814a614b-314f-4b7f-9d03-d49ed1c59f2d/33+TAR.png)
33. BBDFA: A Practical Reagent for Trifluoromethylation of Allylic and Benzylic Alcohols on Preparative Scale
Han, C.;* Alabanza, L. M.; Kelly, S. M.; Orsi, D. L.; Gosselin, F.; Altman, R. A.*
![32. Organocatalytic Strategy for Hydrophenolation of gem-Difluoroalkenes](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/8051a22c-10be-4b86-aaa2-d5548256cee0/32+TAR.png)
32. Organocatalytic Strategy for Hydrophenolation of gem-Difluoroalkenes
Orsi, D. L.; Yadav, M. R.; Altman, R. A.*
![31. Synthesis of C2-Deutero-L-Tryptophan by Sequential Ir-Catalyzed Reactions](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/d0a26a2d-485c-4b13-8dc1-4332d419b18d/31+TAR.png)
31. Synthesis of C2-Deutero-L-Tryptophan by Sequential Ir-Catalyzed Reactions
Vallakati, R. K.; Plotnikov, A. T.; Altman, R. A.*
![30. Catalytic One-Step Deoxytrifluoromethylation of Alcohols](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/685774b5-b1e8-4a96-8651-24c28baa26a4/30+TAR.png)
30. Catalytic One-Step Deoxytrifluoromethylation of Alcohols
de Azambuja, F.; Lovrien, S. K.; Ross, P.; Ambler, B. R.; Altman, R. A.*
![26. Exploiting the Unusual Effects of Fluorine in Methodology](https://images.squarespace-cdn.com/content/v1/615f42729a3e7155f1428c2e/f67a0baf-883f-4ba1-81c5-121698ec211e/26+TAR.png)